Visualization of Photoresponsive Monolayers Comprised of Photochromic Polymers

Takahiro SEKI

doi:10.1380/jsssj.19.598

光伸縮性フォトクロミックポリマー単分子膜の可視化

関隆広

著者情報

ジャーナルフリー

1998 年 19 巻 9 号 p. 598-605

DOI https://doi.org/10.1380/jsssj.19.598

詳細

発行日: 1998/09/10 受付日: 1997/09/22 J-STAGE公開日: 2009/08/07 受理日: 1997/09/22 早期公開日: - 改訂日: -
訂正情報
訂正日: 2009/08/07 訂正理由: - 訂正箇所: 引用文献情報訂正内容: Wrong : 2) M. Irie: Adv. Polym. Sci. 94, 27 (1990).
6) T. Seki and T. Tamaki: Chem. Lett. 1739 (1993).
7) T. Seki, R. Fukuda, M. Yokoi, T. Tamaki and K. Ichimura: Bull. Chem. Soc. Jpn. 69, 2375 (1996).
8) T. Seki, K. Ichimura, R. Fukuda, T. Tamaki, M. Yokoi and K. Ichimura: Polym. J. 28, 613 (1996).
10) M. Lösche, E. Sackmann and H. Möhwald: Ber. Bunsen-Ges. Phys. Chem. 87, 848 (1983).
11) B. Tieke and K. Weiss: J. Colloid Interface Sci. 101, 129 (1984).
12) B. Hönig and D. Möbius: J. Phys. Chem. 95, 4590 (1991).
13) S. Henon and J. Meunier: Rev. Sci. Instrum. 62, 936 (1991).
14) M. Yoneyama, A. Fujii, S. Kasuya, S. Maeda and T. Murayama: J. Phys. Chem. 97, 5124 (1993).
15) R.C. Ahuja, J. Maack and H. Tachibana: J. Phys. Chem. 99, 9221 (1995).
16) Y. Tabe and H. Yokoyama: Langmuir 11, 4609 (1995).
17) O. Karthaus, M. Shimomura, M. Hioki, R. Tahara and H. Nakamura: J. Am. Chem. Soc. 118, 9174 (1996).
18) T. Seki, H. Sekizawa and K. Ichimura: Polym. Commun. 38, 725 (1997).
19) K. Hirano and H. Fukuda: Langmuir 11, 4173 (1995).
20) T. Kajiyama, Y. Oishi, M. Uchida, N. Morotomi, J. Ishikawa and Y. Tanimoto: Bull. Chem. Soc. Jpn. 65, 864 (1992).
21) T. Seki, H. Sekizawa, K. Kudo, Y. Hayashi and K. Ichimura: Mol. Cryst. Liq. Cryst. 294, 47 (1997).
22) T. Seki, H. Sekizawa, S. Morino and K. Ichimura: Joint Symposia “Supermolecules and Nano-Organized Systems,” Fukuoka December 5-6 (1996), p.144.
23) T. Seki, H. Sekizawa, S. Morino and K. Ichimura: J. Phys. Chem. B 102, 5313 (1998).
24) T. Seki, K. Tanaka and K. Ichimura: Adv. Mater. 9, 561 (1997).
25) T. Seki, K. Tanaka and K. Ichimura: Macromolecules 30, 6401 (1997).
26) D. Beaglehole, E.Z. Radlinska, B.W. Ninham and H.K. Christenson: Phys. Rev. Lett. 66, 2084 (1991).
27) M. Matsumoto, D. Miyazaki, M. Tanaka, R. Azumi, E. Maeda, Y. Kondo, N. Yoshino and H. Tachibana: J. Am. Chem. Soc. 120, 1479 (1998).

Right : 2) M. Irie: Adv. Polym. Sci. 94, 27 (1990).
6) T. Seki and T. Tamaki: Chem. Lett. 1739 (1993).
7) T. Seki, R. Fukuda, M. Yokoi, T. Tamaki and K. Ichimura: Bull. Chem. Soc. Jpn. 69, 2375 (1996).
8) T. Seki, K. Ichimura, R. Fukuda, T. Tamaki, M. Yokoi and K. Ichimura: Polym. J. 28, 613 (1996).
10) M. Lösche, E. Sackmann and H. Möhwald: Ber. Bunsen-Ges. Phys. Chem. 87, 848 (1983).
11) B. Tieke and K. Weiss: J. Colloid Interface Sci. 101, 129 (1984).
12) B. Hönig and D. Möbius: J. Phys. Chem. 95, 4590 (1991).
13) S. Henon and J. Meunier: Rev. Sci. Instrum. 62, 936 (1991).
14) M. Yoneyama, A. Fujii, S. Kasuya, S. Maeda and T. Murayama: J. Phys. Chem. 97, 5124 (1993).
15) R.C. Ahuja, J. Maack and H. Tachibana: J. Phys. Chem. 99, 9221 (1995).
16) Y. Tabe and H. Yokoyama: Langmuir 11, 4609 (1995).
17) O. Karthaus, M. Shimomura, M. Hioki, R. Tahara and H. Nakamura: J. Am. Chem. Soc. 118, 9174 (1996).
18) T. Seki, H. Sekizawa and K. Ichimura: Polym. Commun. 38, 725 (1997).
19) K. Hirano and H. Fukuda: Langmuir 11, 4173 (1995).
20) T. Kajiyama, Y. Oishi, M. Uchida, N. Morotomi, J. Ishikawa and Y. Tanimoto: Bull. Chem. Soc. Jpn. 65, 864 (1992).
21) T. Seki, H. Sekizawa, K. Kudo, Y. Hayashi and K. Ichimura: Mol. Cryst. Liq. Cryst. 294, 47 (1997).
22) T. Seki, H. Sekizawa, S. Morino and K. Ichimura: Joint Symposia “Supermolecules and Nano-Organized Systems,” Fukuoka December 5-6 (1996), p.144.
23) T. Seki, H. Sekizawa, S. Morino and K. Ichimura: J. Phys. Chem. B 102, 5313 (1998).
24) T. Seki, K. Tanaka and K. Ichimura: Adv. Mater. 9, 561 (1997).
25) T. Seki, K. Tanaka and K. Ichimura: Macromolecules 30, 6401 (1997).
26) D. Beaglehole, E.Z. Radlinska, B.W. Ninham and H.K. Christenson: Phys. Rev. Lett. 66, 2084 (1991).
27) M. Matsumoto, D. Miyazaki, M. Tanaka, R. Azumi, E. Maeda, Y. Kondo, N. Yoshino and H. Tachibana: J. Am. Chem. Soc. 120, 1479 (1998).

抄録

Photomechanical response of the polymer monolayers having an azobenzene (Az) side chain was successfully visualized by Brewster angle microscopy (BAM) and atomic force microscopy (AFM). In situ BAM observation that covers the sub-millimeter scale range revealed clear photoinduced morphological and rheological changes. By following the photoinduced morphological changes of an isolated single domain, a couple of hitherto unknown properties have been unveiled, for example, non-linearity involved in the film expansion process, intrinsic magnitude of film expansion at zero pressure, dependence on light intensity and so forth. By AFM that observes the ranges of micrometer to nanometer levels, it was found that even on a mica surface, the Az containing monolayer shows a reversible photoinduced film deformation under highly humid conditions. These visualization techniques provided a great deal of complementary unique information which covers the scale ranges between the macroscopic Langmuir trough experiments and scale spectroscopic observations at a molecular level.

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