An Approach for the Study on Supported Metal Catalysts with Model Catalysts

Yoshio Takasu; Yoshiharu Matsuda

doi:10.1380/jsssj.2.146

担持金属触媒研究におけるモデル触媒によるアプローチ

高須芳雄, 松田好晴

著者情報

ジャーナルフリー

1981 年 2 巻 2 号 p. 146-151

DOI https://doi.org/10.1380/jsssj.2.146

詳細

発行日: 1981/06/01 受付日: 1980/12/22 J-STAGE公開日: 2009/08/07 受理日: 1980/12/22 早期公開日: - 改訂日: -
訂正情報
訂正日: 2009/08/07 訂正理由: - 訂正箇所: 引用文献情報訂正内容: Wrong : 1) J. M. Dartigues, A. Chambellan and F. G. Gault, J. Am. Chem. Soc., 98 (1976) 856.
2) G. C. Bond, Proc. 4th Internl. Congr. Catalysis, Moscow (1968) p. 266.
3) P. H. Otero-Schipper, W. A. Wachter, J. B. Butt, R. L. Burmell and Jr. J. B. Cohen, J. Catalysis, 53 (1978) 414.
4) D. J. C. Yates, L. L. Murrell and E. B. Prestridge, J. Catalysis, 57 (1979) 41.
7) Y. Takasu, R. Unwin, B. Tesche, A. M. Bradshaw and M. Grunze, Surface Science, 77 (1978) 219.
8) J. F. Hamilton and P. C. Logel, Thin Solid Films, 16 (1973) 49.
10) M. G. Mason, L.J. Gerenser and S.T. Lee, Phys. Rev. Lett., 39 (1977) 288.
11) K. S. Kim and N. Winograd, Chem. Phys. Lett., 30 (1975) 91.
12) R. C. Baetzold, J. Appl. Phys., 47 (1976) 3799.
13) G. Apai, J. F. Hamilton, J. Stohr and A. Thompson, Phys. Rev. Lett., 43 (1979) 165.
14) J. F. Hamilton and P. C. Logel, J. Catalysis, 29 (1973) 253.
15) S. Ino, J. Phys. Soc. Japan, 21 (1966) 346.
16) T. Komoda, Japan. J. Appl. Phys., 7 (1968) 27.
17) K. Kimoto and I. Nishida, J. Phys. Soc. Japan, 42 (1977) 2071.
18) Proc. Internl. Conf. Matrix Isolation Spectroscopy, Berlin (1977), in Ber. Bunsengesell. Phys. Chem., 82 (1978) 1.
19) H. Conrad, G. Ertl, H. Knözinger, J. Küppers and E. E. Latta, Chem. Phys. Lett., 42 (1976) 115.
20) M. Ichikawa, Chem. Lett., 1976, 335.
21) R. van Hardeveld and F. Hartog, Surface Science, 15 (1969) 75.
22) M. Mason and R. C. Baetzold, J. Chem. Phys. 64 (1976) 271.
23) R. C. Baetzold, M. G. Mason and J. F. Hamilton, J. Chem. Phys, 72 (1980) 366.
24) K. Kubo, Comments Solid State Phys, 1(1968) 61.
25) J. R. Anderson, “Structure of Metallic Catalysts”, Academic Press, N. Y. (1975) p. 244.
26) Y. Takasu and A. M. Bradshaw, Chem. Phys. Solid & Surfaces, 7 (1978) 59.

Right : 1) J. M. Dartigues, A. Chambellan and F. G. Gault, J. Am. Chem. Soc., 98 (1976) 856.
2) G. C. Bond, Proc. 4th Internl. Congr. Catalysis, Moscow (1968) p. 266.
3) P. H. Otero-Schipper, W. A. Wachter, J. B. Butt, R. L. Burmell and Jr. J. B. Cohen, J. Catalysis, 53 (1978) 414.
4) D. J. C. Yates, L. L. Murrell and E. B. Prestridge, J. Catalysis, 57 (1979) 41.
7) Y. Takasu, R. Unwin, B. Tesche, A. M. Bradshaw and M. Grunze, Surface Science, 77 (1978) 219.
8) J. F. Hamilton and P. C. Logel, Thin Solid Films, 16 (1973) 49.
10) M. G. Mason, L.J. Gerenser and S.T. Lee, Phys. Rev. Lett., 39 (1977) 288.
11) K. S. Kim and N. Winograd, Chem. Phys. Lett., 30 (1975) 91.
12) R. C. Baetzold, J. Appl. Phys., 47 (1976) 3799.
13) G. Apai, J. F. Hamilton, J. Stohr and A. Thompson, Phys. Rev. Lett., 43 (1979) 165.
14) J. F. Hamilton and P. C. Logel, J. Catalysis, 29 (1973) 253.
15) S. Ino, J. Phys. Soc. Japan, 21 (1966) 346.
16) T. Komoda, Japan. J. Appl. Phys., 7 (1968) 27.
17) K. Kimoto and I. Nishida, J. Phys. Soc. Japan, 42 (1977) 2071.
18) Proc. Internl. Conf. Matrix Isolation Spectroscopy, Berlin (1977), in Ber. Bunsengesell. Phys. Chem., 82 (1978) 1.
19) H. Conrad, G. Ertl, H. Knözinger, J. Küppers and E. E. Latta, Chem. Phys. Lett., 42 (1976) 115.
20) M. Ichikawa, Chem. Lett., 1976, 335.
21) R. van Hardeveld and F. Hartog, Surface Science, 15 (1969) 75.
22) M. Mason and R. C. Baetzold, J. Chem. Phys. 64 (1976) 271.
23) R. C. Baetzold, M. G. Mason and J. F. Hamilton, J. Chem. Phys, 72 (1980) 366.
24) K. Kubo, Comments Solid State Phys, 1(1968) 61.
25) J. R. Anderson, “Structure of Metallic Catalysts”, Academic Press, N. Y. (1975) p. 244.
26) Y. Takasu and A. M. Bradshaw, Chem. Phys. Solid & Surfaces, 7 (1978) 59.

抄録

An application of model catalysts has been presented as one of the methods for investigating the catalytic properties of supported metal catalysts. The model catalysts can be prepared in situ by vacuum evaporation onto an amorphous substrate (film of SiO₂, Al₂O₃, or carbon) and studied by such techniques as photoelectron and Auger electron spectroscopy; industrial supported metal catalysts are unsuitable for such techniques using UHV systems. Ensembles prepared in this way offer the possibility of investigating not only the physical properties of particles but also their surface reactivity with simple gases. Apart from the interest in model catalysts, the small metal particles themselves deserve attention; the electronic properties of metal aggregates in size ranges where discrete valence band levels are expected have scarcely been examined. The advantages and application methods of the model catalysts are introduced as well as recent literature on the electronic properties of small metal particles and other approaches for this field.

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