Abstracts of Symposium on Physical Organic Chemistry
22nd Symposium on Physical Organic Chemistry
Session ID : A28
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Location A
Self-Assembled Cavitand-Capsule Based on Dynamic Boronic Ester Bonds
*Kenji KobayashiYohei HirumiAsumi IshigamiKento Tamaki
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CONFERENCE PROCEEDINGS FREE ACCESS

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Abstract
Recently, we have reported the self-assembly of two molecules of cavitand tetraboronic acid and four molecules of 1,2-bis(3,4-dihydroxyphenyl)ethane into a capsule via dynamic boronic ester bond formation. Here, we describe recent topics of the boronic ester capsule: (1) the use of the capsule as a guard nanocontainer to protect against photochemical reactions of anthracene derivatives as guests, (2) tunable capsule space by the self-assembly of the cavitand tetraboronic acid with various types of bis(catechol)-linkers, and (3) the linker exchange reaction between two types of capsules.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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