2007 Volume 48 Issue 5 Pages 919-923
In equilibrium binary W-C system, mono-carbide WC is acknowledged as the stable phase under presence of excess free carbon up to temperature 2700°C whereas sub-carbide W2C would form between 1250°C and 2700°C under the carbon-deficiency condition. In unique setup of solar furnace at PROMES-CNRS in Odeillo (France), temperature of specimen is raised from the ambient temperature to target temperature up to 2000°C within fractions of a second. In the recent experimental attempts of W2C phase synthesis using this unique experimental facility starting from compacted pellet consisted of graphite and tungsten powders at ratios smaller than 0.50, we detected growth of nano-meter size WC whisker at the top surface directly exposed to the concentrated solar beam. The presence of WC was confirmed also by X-ray diffraction (XRD) of the top surface but, when the specimen as a whole was subjected to powder XRD analysis, WC became indiscernible being masked by principal W2C phase. Mechanism of formation of the detected WC nano-whisker over sub-stoichiometric C/W pellet during ultra-fast heating by concentrated solar beam is discussed.