MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
Kinetics of Solid-State Reactive Diffusion in the Cu/Zn System
Yoshiki TakamatsuMinho OMasanori Kajihara
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2017 Volume 58 Issue 1 Pages 16-22

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Abstract

The kinetics of the solid-state reactive diffusion between pure Cu and Zn was experimentally examined using sandwich Zn/Cu/Zn diffusion couples prepared by a diffusion bonding technique. The diffusion couples were isothermally annealed in the temperature range of 523–623 K for various times up to 49 h. Owing to annealing, an intermetallic layer consisting of the γ and ε phases was formed at the original interface in the diffusion couple, where the thickness is much smaller for the ε phase than for the γ phase. The total thickness of the intermetallic layer increases in proportion to a power function of the annealing time. The exponent of the power function takes values of 0.60–0.62 at 523–623 K. These values of the exponent indicate that volume diffusion predominantly controls the layer growth and interface reaction partially contributes to the rate-controlling process.

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© 2016 The Japan Institute of Metals and Materials
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