cα記πα一μ一工チニレンーフタロシアニナトコバルト(III)の合成とその導電性

抄録

catena-μ-Ethynylene-phthalocyaninatocobalt(III) was synthesized by the reaction of dichlorophthalocyaninatocobalt(III) with bis(bromomagnesio)acetylene. This polymer was regarded as a novel type of an one-dimensional polymer, consisting of phthalocyanine radical species. The one-dimensional structure of this polymer was confirmed by IR spectrum and X-ray analysis. The conductivity of this polymer was found to be 3×10^-4 S/cm at room temperature without doping. This conductivity was explained by an increase of the carriers induced by the radical phthalocyanine rings.