1979 Volume 28 Issue 11 Pages 681-686
A chelating agent-loaded resin consisting of 8-quinolinol-5-sulfonic acid and an anion-exchange resin (HOx-resin) was prepared in order to concentrate trace chalcophile elements in natural water samples selectively before neutron activation analysis. The exchange capacity of the Diaion SA# 100 for the reagent (1.8 meq⋅g-1 resin) corresponds approximately to that for chloride ion (1.83 meq⋅g-1 resin), indicating that 8-quinolinol-5-sulfonic acid is adsorbed quantitatively on the exchange site of the resin through the sulfonate anion in the reagent.
The basic conditions for the adsorption of the metal ions on the resin were investigated by employing the column method. The nitrate concentration and the pH of the sample solution affect the adsorption behavior of metal ions. Several solutions containing metal ions with vary-ing pH or varying nitrate concentration were applied to the resin column (35 mm×7 mmφ) with a flow rate of 2.0 cm3⋅min-1.
As a result, the optimum conditions for the quantitative adsorption of copper (II), zinc (II), cadmium (II), cobalt (II), nickel (II) and manganese (II) were as follows: NO3- <0.01 mol⋅dm-3 pH >4.6. Furthermore, the feasibility of the above conditions as well as quantitative adsorption of the chalcophile elements was confirmed through the neutron activation analysis of the synthesized metal solutions.
