成形加工
Online ISSN : 1883-7417
Print ISSN : 0915-4027
論文
フィラー/PP複合材料の熱劣化機構とその抑制
細井 啓史船見 文寧安田 直樹野村 学由井 浩幾田 信生
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ジャーナル フリー

19 巻 (2007) 6 号 p. 375-380

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To examine thermal degradation accelerated by filling inorganic particles in polypropylene (PP), the composites were made with three types of inorganic powders : talc, magnesium hydroxide, and mica. They were easily degraded with the fillers in this order in the thermal aging test. A commercial heat resistance agent, ‘Plenlizer MK-400’, was added while making the composites. The degradation resistance of the agent remarkably appeared in the reverse order. That is, thermal degradation was most depressed in talc-filled composite with the agent. In another experience, soxhlet extraction was carried out to the filler with an organic solvent, o-xylene, that was able to dissolve PP. A lot of inorganic ions were detected in the extractant. In particular, the detected amount of aluminum ion increased in the order of talc, magnesium hydroxide, and mica. This order was the same as the fillers indicated by the degree of degradation. Infrared analysis of the agent with inorganic ions in chloroform showed that the peaks due to the agent were much stronger with aluminum ion than those with iron ion. These results suggested that a cause of degradation was aluminum ion dispersed from particles to PP matrix during the molding.

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© 2007 一般社団法人 プラスチック成形加工学会
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