2009 年 60 巻 3 号 p. 174
Dielectric barrier discharge (DBD), properly combined with porous ceramics and/or catalysts, is a promising technology for diesel exhaust gas treatment. In this study, anodic porous alumina, which has numerous pores with nanometer-order diameter and a high aspect ratio, has been examined for use as a barrier in a DBD reactor. The anodic porous alumina greatly improves the DBD reactor. Nevertheless, few reports describe DBD using the anodic porous alumina barrier. As described herein, the DBD reactor’s basic characteristics and NOx removal in atmospheric pressure air were studied to support its future development. Results were compared with those of a typical DBD to clarify the influence of anodic porous alumina on those characteristics.
The electropolished 99.99% pure Al substrate was anodized in 1.0 M sulfuric acid of 10°C for 5 h at dc 24 V. The Al substrate and anodic porous alumina respectively act as the electrode and dielectric barrier of the DBD. The dry gas mixture of NO (several hundred ppm) / O2 (20%) / N2 was supplied into the DBD reactor at 1.0 L/min. The resultant voltage and current waveforms resembled those of a typical DBD. Results revealed that NO was mostly oxidized to NO2 ; about 20 ppm N2O was detected. Different from a typical DBD the NO2 increased characteristically as a function of operation time.
