This study investigated the electrodeposition of Mo from anhydrous MoCl5 and Na2MoO4 in various organic solvents; HCONH2, HCONH2-CH3CONH2, OCH2CH2CH2CH2, HCON (CH3)2, CH2(CH2)4NC; N(CH2)2CH2 and (CH3)2SO.
Bright deposits of Mo were obtained from 15g/L∼40g/L Na2MoO4, HCONH2 or HCONH2-CH3CONH2 under 30A/dm2, 100°C and 60∼90min, plating time. The deposits obtained were Mo-Pt alloy films.