浴安定性に優れたヒドラジンを還元剤とした無電解ニッケルめっき

抄録

An electroless nickel plating bath with a hydrazine reducing agent has been investigated. An electroless nickel plating bath with a deposition rate of about 3μm/hr and superior bath stability as compared to previously reported bath has been developed. The new bath is a simple system consisting of glycine and boric acid in addition to nickel and hydrazine. The optimum plating conditions for the bath are in the range of 85-90°C at a pH of 12. The deposits obtained from the developed bath are black with a surface morphology that has a dendrite structure. Characteristics of deposits such as specific resistance and solderability were superior to those of conventional nickel-phosphorus deposits. Results confirmed that nickel was directly deposited on a copper substrate from an electroless nickel plating bath with a hydrazine reducing agent without an activation step in pretreatment.