日本鉱業会誌
Online ISSN : 2185-6729
Print ISSN : 0369-4194
FeS-FeO-B2O3系およびFeS-FeO-P2O5系における相分離と製錬融体の不混和性
Antonio K. ESPELETA氏家 速雄矢沢 彬
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ジャーナル フリー

1988 年 104 巻 1210 号 p. 909-913

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Phase separation behavior between a molten sulfide and molten oxide is investigated in a FeS-FeO-AO ternary system where AO is a strong acidic oxide such as B2O3or P2O5. Experimental results indicate that a wide miscibility gap occurs along the increment of a strong acidic oxide component, The immiscibility behavior based on the experimental results is compared with a previous work on the FeS-FeO-SiO2system to describe the effect of a strongacidicoxide component on the phase separation between molten matte (sulfide) and slag (oxide). Basedupon the regular solution model, ternary immiscibilities for various smelting systems are explained thermodynamically from the binary data.
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© The Mining and Materials Processing Institute of Japan
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