Journal of the Japan Society of Colour Material
Online ISSN : 1883-2199
Print ISSN : 0010-180X
ISSN-L : 0010-180X
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Intermolecular Interactions Induced by Full Fluorination: Molecular Recognition of Solid Materials Using Opposite Quadrupole Moment
Akiko HORI
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2019 Volume 92 Issue 9 Pages 274-278

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Abstract

Fluorine is a unique substituent that dramatically changes the intramolecular electron withdrawing nature and intermolecular interactions of aromatic materials without significantly changing their color or molecular structure. Herein, we introduce the quadrupole moments of aromatic compounds and the corresponding fluorinated compounds and discuss molecular recognitions of non-polar compounds, such as benzene and carbon dioxide, in non-porous crystals of fully fluorinated coordination complexes for their application to solid materials.

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© 2019 Japan Society of Colour Material
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