Investigation of Oxygen Partial Pressure to Improve Photoluminescence Intensity for Li-Ta-Ti-O:Mn⁴⁺ Phosphors Using Air-pressure Control Atmosphere Furnace

Abstract

The photoluminescence (PL) intensities of Li-Ta-Ti-O:Mn⁴⁺ red phosphors were successfully improved under various oxygen partial pressures in an air-pressure control atmosphere furnace (APF). The Mn phosphors were synthesized using an APF and a conventional electric furnace (EF) with the composition formula Li_1.33Ta_0.67Ti_0.33O₃ as the host material. The effects of oxygen partial pressure on the Mn⁴⁺ ratio and crystal structure for the PL intensity were investigated. As a result, the PL intensity was enhanced under high oxygen partial pressure, showing about 2.6 times higher than the phosphor synthesized by EF.