溶鋼へのガス吹込み時の物質移動係数と撹拌強度の関係

抄録

Nitrogen gas absorption phenomena in molten steel during bottom bubbling were experimentally studied. Changes of nitrogen in molten steel were observed with 10, 14 and 200 kg scale experiments and it was confirmed that absorption rate of nitrogen were controlled by mass transfer. In addition, bubble dispersions in each experiments were visualized with volume of fluid method (VOF) solver of OpenFOAM and the area of free surface, A_S and bubble, A_B were numerically evaluated.

The measured data were evaluated with a mixed control model of liquid-phase, gas-phase and chemical reaction. Numerically evaluated A_S and A_B were utilized for separation from volumetric rate constant of nitrogen absorption, Ak_m to mass transfer coefficient, k_m. As a result, mass transfer coefficient at bubble, k_m,B and free surface, k_m,S were obtained. In addition, relation between stirring power density, ε ˙ and both k_m,B and k_m,S were investigated and it was revealed that k_m,B and k_m,S increased in proportion to ε ˙ ^0.6.