Tetsu-to-Hagane
Online ISSN : 1883-2954
Print ISSN : 0021-1575
ISSN-L : 0021-1575
Thermodynamics of Phosphorus in CaO-K2O-CaF2-SiO2 Melts
Hisao KIMURAFumitaka TSUKIHASHI
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1997 Volume 83 Issue 11 Pages 689-694

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Abstract

The effect of K2O addition to the CaO-CaF2-SiO2 flux on the phosphorus partition ratio between CaO-CaF2-SiO2 flux doubly saturated with CaO and 3CaO·SiO2 and carbon saturated iron melts has been investigated at 1473, 1523 and 1573K by a chemical equilibration technique. The partition ratio increases with increasing the K2O content. The phosphate capacity of CaO-K2O-CaF2-SiO2 flux was compared with various basic fluxes. The activity of K2O in the CaO-CaF2-SiO2 system doubly saturated with CaO and 3CaO·SiO2 has been determined at 1573K which rangs from 10-13 to 10-12.

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© The Iron and Steel Institute of Japan
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