1998 Volume 84 Issue 11 Pages 797-803
The enhancement of ferrite nucleation owing to vanadium nitride (VN) precipitated in the austenite phase was studied for a 0.14%C-1.45%Mn-0.06%V-0.009%N steel and the isothermal ferrite transformation behavior associated with VN precipitation was also quantitatively discussed.
Vanadium nitrides precipitate on the austenite grain boundary in preference to the grain interior and increase the density of grain boundary ferrites. On the other hand. VN precipitates in austenite grain interior are less effective to intragranular ferrite nucleation. The calculation based on the classical nucleation theory shows that the activation energy of VN precipitates for a critical ferrite nucleus formation is one-fifth lower than that in case of no precipitate. The ferrite nucleation potency of VN precipitates is kept high even in higher temperature range above 700°C.