オレフィン系冷媒R 1234yf およびR 1234ze(E) の熱力学性質に関する研究動向

抄録

A comprehensive review is presented for the study on the thermodynamic properties of R 1234yf (2,3,3,3- tetrafluoropropene) and R 1234ze(E) (trans-1,3,3,3-tetrafluoropropene), which are considered as a possible replacement for conventional refrigerants with far from negligible global warming potential. Available experimental data for the critical parameters, vapor pressures, liquid/vapor densities, heat capacities, and speeds of sound are compiled, and reliability of each data is evaluated. A brief summary is also given for equations of state developed for these refrigerants, including comparison of deviations from experimental values and valid ranges of each equation of state. Recommended equations are selected which can be applied to refrigeration system analysis.