Nitrogen and Hydrogen Gas Adsorption Properties of Microporous Ruthenium Coordination Polymers

抄録

We investigated nitrogen and hydrogen gas adsorption properties of microporous ruthenium coordination polymers constructed from Ru^II/III₂ paddle wheel motif and dicarboxylic organic linkers such as terepthalic acid, fumaric acid, muconic acid and succinic acid. In nitrogen gas adsorption measurements, we calculated adsorption parameters such as surface area (Langmuir ), pore volume and pore diameter. The relation between adsorption parameters and maximum amount of hydrogen uptake was discussed.