Transactions of the Materials Research Society of Japan
Online ISSN : 2188-1650
Print ISSN : 1382-3469
ISSN-L : 1382-3469
Regular Papers
Polymer-Supported Terpyridine–Palladium Complex for the Aminocarbonylation in Water of Aryl Iodines Using Methoxylamine Hydrochloride as an Ammonia Equivalent
Toshimasa SuzukaHiromu SueyoshiKazuhito Ogihara
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2016 Volume 41 Issue 3 Pages 225-228

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Abstract

  A novel homogeneous transition-metal catalyst, a polymer-supported terpyridine–palladium(II) complex, was found to promote the aminocarbonylation of aryl iodines using methoxylamine under phosphine-free conditions in water with good yield. The catalyst was recovered and reused several times without loss of catalytic activity. To our knowledge, this is the first example of polymer-supported, palladium-catalyzed synthesis of primary amides by aminocarbonylation of aryl iodides and methoxylamine under phosphine-free conditions in water.

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© 2016 The Materials Research Society of Japan
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