表面と真空
Online ISSN : 2433-5843
Print ISSN : 2433-5835
特集「2018年日本表面真空学会学術講演会特集号III」
パラジウム薄膜の準安定水素化物形成とその緩和の観測
小澤 孝拓清水 亮太小倉 正平一杉 太郎福谷 克之
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2019 年 62 巻 8 号 p. 492-497

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We fabricated metastable palladium hydride by hydrogen ion implantation to a 10 nm-thick Pd film at 7 K, and monitored the hydride formation and relaxation to a stable state by resistivity measurements. By heating the sample, we observed a substantial change in resistivity below 100 K without accompanying hydrogen desorption. While the resistivity change was observed at 80 K for both H and D, it was observed only for H at 6 K. This irreversible resistivity change is attributed to transition from the metastable state to its stable state by hydrogen diffusion. It is considered that hydrogen atoms undergo diffusion thermally at 80 K and by quantum tunneling at 6 K.

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この記事はクリエイティブ・コモンズ [表示 - 非営利 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc/4.0/deed.ja
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