NMRによるLewis塩基とTris(dipivaloylmethanato)europium間の会合定数と錯体シフトの簡易決定法について

抄録

Both association constant and bound chemical shift are estimated by a simple graphic method under equimolar conditions for the association between Lewis base and tris (dipivaloylmethanato) europium in CCl₄ or cyclohexane by using 1n Δ=-K₁^-1/2·C_B^O-1/2+1n Δ₁. This method can be applied in the conditions of K₁C_B^O≳0.45 and the result is correlated successfully with the value estimated from the computer simulation.