YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
含窒素複素環化合物の研究(第48報)N-Acylbenzo[f]quinolinium ChlorideとTrialkyl PhosphiteとのReissert Typeの反応 その1
竹内 烈柴田 恭裕濱田 喜樹
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1984 年 104 巻 11 号 p. 1133-1139

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The reaction of benzo [f] quinoline (1) with various acyl chlorides and trimethyl phosphite in the presence of sodium iodide gave the corresponding N-heterocyclic α-phosphonate (2) and γ-phosphonate (3). In the similar reaction using bulky phosphites, the ratios [2/3] were changed by a steric effect between the benzo [f] quinoline and the trialkyl phosphite.

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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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