遷移金属触媒及びルイス酸触媒による高選択的不斉反応の立体化学
1995 年 115 巻 8 号 p. 553-569
詳細
1995 年 115 巻 8 号 p. 553-569
Recent progress of our studies on catalytic asymmetric synthesis is reviewed focused on transition metal-catalyzed intramolecular asymmetric reactions using chiral organo-sulfur groups as main chiral auxiliaries such as asymmetric vinylcyclopropane-cyclopentene rearrangements and intramolecular asymmetric metallo-ene reactions, Lewis acid-catalyzed intramolecular asymmetric ene reactions with chiral sulfinyl groups, and palladium-catalyzed intramolecular asymmetric allylations via chiral enamines.
