還元的アチルアミン化の研究 (第4報)
アンモニアの存在に於けるカルボニル化合物の還元的アチルアミン化
1950 年 70 巻 10 号 p. 548-551
詳細
1950 年 70 巻 10 号 p. 548-551
Hydrogenation of carbonyl compounds over Raney nickel at high temperature and high pressure in the presence of ammonia and formamide gave formylamino derivatives. The carbonyl compounds used were benzaldehyde, p-sulfonamidobenzaldehyde, n-butyraldehyde, acetophenone and phenylacetone. The yield of formamides was good in aromatic carbonyl compounds, side reaction being suppressed. Yield of formylamino derivatives were comparatively poor from aliphatic carbonyl compounds.
