スルフォンアマイドの研究 第5報

N-ニトロゾスルフォンアマイドの研究

抄録

N-nitroso-p-toluenesulfomethylamide and N-nitroso-p-toluenesulfobenzylamide were synthesized and the behavior of their N-nitroso radical was studied. The reaction with hydrocarbons give, not nitroso compounds, but esters of p-toluenesulfonic acid by liberation of nitrogen in thermal decomposition, and, in the case of benzyl compound, formation of benzaldehyde as well.
This reaction is similar to decomposition of N-nitrosoacetanilide and can well be explained by the reaction mechanism proposed for it. N-nitrososulfonamide also undergoes nitrosation reaction at temperatures below its decomposition point, e. g. forming N-nitrosodiphenylamine from diphenylamine.