YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
結核菌に含まるる枝鎖脂肪酸類の合成研究 (第9報)
フチオン酸に関する研究 (VII) コルベ電解による11,15-ヂメチルパルミチン酸の合成
諸江 辰男
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1951 年 71 巻 2 号 p. 121-123

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In order to obtain 3, 13, 19-trimethyltricosanoic acid, which is assumed to be the structure of phthioic acid, by the Kolbe's electrolytic condensation of 6-methyldecanoic acid and ethyl hydrogen 2, 12-dimethyltridecane-1, 13-dicarboxylate 11, 15-dimethylpalmitic acid was prepared by the Kolbe's electrolytic condensation of dihydrorhodinic acid and ethyl hydrogen sebacate, as a model experiment of electrolytic reaction, with an yield of 31%. In this reaction, 2, 6, 9, 13-tetramethyltetradecane and hexadecane-1, 16-dicarboxylic acid were recognized to be byproducts.

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