N-Glycosideの過沃度酸々化に就いて (第2報)

抄録

Periodic acid was applied to o-, m- and p-toluidine, m- and p-nitraniline, o-, m-, and p-aminobenzoic acid, aniline, monoethylaniline and its hydrochloride, dimethylaniline, and diphenylamine, and it was found that all these compounds, with the exception of nitranilines, absorbed the said oxidant at the same reaction rate as those of α-glycols. Moreover, the periodical progress of these reactions were found to be closely similar to the portion of periodical curve above 5 moles of absorption of periodic acid by arylamine-N-glucoside from which it was realized that the oxidation of arylamine-N-glucoside by above 5 moles of periodic acid was not due to formic acid and formaldehyde but by the action of liberated arylamine itself.