YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Acylamino化合物の酸化に依るNitro化合物の合成 (第7報)
過酸化水素酸化に於ける副反応及び反応機作の考察
小菅 卓夫宮下 修一
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1954 年 74 巻 12 号 p. 1381-1383

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1) Side-reactions that occur during oxidation of acylamino compounds with hydrogen peroxide was examined and the chief side-reaction was found to be the formation of ammonia. The cause of this reaction was assumed.
2) The yield of the nitro compound was found to decrease markedly when glacial acetic acid is not used as the solvent. In this case, the amine formed by the hydrolysis of the acetamino group was isolated and it was assumed that hydrogen peroxide also caused hydrolysis.

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