YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
ジアリルジサルファイド系化合物の製造法の研究 (第4報)
ヨウ素触媒の共存下に赤燐を用いるスルホニルクロライドの還元反応 その3
河原 清
著者情報
ジャーナル フリー

1957 年 77 巻 9 号 p. 969-972

詳細
抄録

It has been shown in the preceding experiment that the process of reducing arenesulfonyl chlorides with red phosphorus in the presence of iodine catalyst is useful for the preparation of diaryl disulfides possessing a reducible group. The process was then applied to arenesulfonyl chlorides possessing hydrolyzable groups, such as cyano, acetamido, and ether and ester bondings. It was thereby learned that depending on the position of the cyano group, the cyano group is hydrolyzed together with the reduction of the sulfonyl chloride group. Other hydrolyzable groups remained intact and corresponding disulfides were obtained.

著者関連情報
© by the PHARMACEUTICAL SOCIETY OF JAPAN
前の記事 次の記事
feedback
Top