YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
ジアリルジサルファイド系化合物の製造法の研究 (第6報)
ヨウ素触媒の存在下で赤燐を用いるフェニルメタンスルホニルクロライドの還元反応 その1
河原 清
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1957 年 77 巻 9 号 p. 977-979

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Some considerations were made on the mechanism of the formation of dibenzyl sulfide (II) by the reaction of phenylmethanesulfonyl chloride (I) with red phosphorus, in the presence of iodine catalyst. A part of (I) is reduced through dibenzyl disulfide to phenylmethanethiol (V). The remaining part of (I) undergoes pyrolysis at the same time to form benzyl chloride (III), which is changed to benzyl iodide (IV) by the action of hydriodic acid. Finally, (II) is formed by the condensation of (V) and (IV).

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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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