YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Dibenzo-p-dioxin誘導体の液安-ナトリウムによる開裂反応 その1
1-Methoxydibenzo-p-dioxinの開裂反応
犬伏 康夫野村 敬一西村 永二山本 幹男
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1958 年 78 巻 11 号 p. 1189-1194

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The product obtained by fission of 1-methoxydibenzo-p-dioxin (II) with sodium and liquid ammonia was examined and two kinds of compounds were found to be formed. One was 3-methoxy-2′-hydroxydiphenyl ether (III) and the other was found to be 2-methoxy-6, 2′-dihydroxybiphenyl (IVa). It was also reavealed that the yield of (III), considered to be the normal reaction product, increased when the reaction temperature was lower and on addition of ammonium chloride during the reaction.

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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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