YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
リン酸化の研究 (第3報)
亜リン酸エステルを経由するPyridoxine 5-Phosphateの合成
田中 照夫
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ジャーナル フリー

1959 年 79 巻 10 号 p. 1301-1305

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Oxidation of pyridoxine 5-phosphite (IV), after acylation, with potassium permanganate and subsequent deacylation affords pyridoxine 5-phosphate (VII) in a good yield. Similarly, 4-N-benzoylpyridoxamine 5-phosphite (XII) affords its 5-phosphate (XIII) in 59% yield. Direct oxidation of (IV) with permanganate affords pyridoxal 5-phosphite (VIII) in 20% yield. Reaction of compounds allied to pyridoxine and diphenyl chlorophosphite was described.

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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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