YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
二, 三のPhenethylamine誘導体の液体アンモニア中アルカリ金属による反応
富田 真雄高野 良宏
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1959 年 79 巻 10 号 p. 1331-1334

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Decomposition reaction of homoveratrylamine (I) and mescaline (V) with metallic sodium in liquid ammonia is comparatively difficult but their demethylation were effected and (I) afforded 3-hydroxy-4-methoxyphenethylamine (II) while (V) formed 4-hydroxy-3, 5-dimethoxyphenethylamine (VI) and a structurally unknown amine, which were obtained as their picrates. The same reaction of homopiperonylamine (III) was effected comparatively either with metallic sodium or lithium, with reductive proceeding solely to form tyramine (IV).

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