シクロヘキシルスルファミン酸塩に関する研究 (第1報)
ニトリドトリスルホン酸アンモニウムとシクロヘキシルアミンとの反応
1961 年 81 巻 11 号 p. 1531-1534
詳細
1961 年 81 巻 11 号 p. 1531-1534
Application of cyclohexylamine, in an amount 1.5-2 times the theoretical quantity, to ammonium nitridotrisulfate and heating the mixture at 170° for 3 hours results in formation of cyclohexylammonium cyclohexanesulfamate in over 90% yield. The amount of ammonia evolved was examined in the reaction of ammonium nitridotrisulfate and cyclohexylamine at 120° and this reaction was considered to be in a following manner:
N(SO3NH4)3+C6H11NH2=N(SO3NH4)2(SO3HC6H11NH2)+NH3
N(SO3NH4)2(SO3HC6H11NH2)+3C6H11NH2=NH(SO3HC6H11NH2)2+C6H11NHSO3HC6H11NH2+2NH3
