YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
D-キシロースよりD-リボースの合成
岡 孝二和田 博
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1963 年 83 巻 9 号 p. 890-891

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5-O-Benzoyl-1, 2-O-isopropylidene-D-xylofuranose was oxidized with di-tert-butyl ether-chromium trioxide to 3-oxo-5-O-benzoyl-1, 2-O-isopropylidene-D-xylofuranose, which was reduced catalytically over Adams platinum in tert-butanol and 5-O-benzoyl-1, 2-O-isopropylidene-D-ribofurane was obtained stereospecifically. Its hydrolysis by the conventional method afforded D-ribopyranose.

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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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