YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
ハスNelumbo nucifera GAERTN. のアルカロイド研究 (第7報)
NuciferineならびにNornuciferineの液体アンモニア中金属ナトリウムによる開裂反応
国友 順一上村 倫子
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1964 年 84 巻 11 号 p. 1100-1104

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Cleavage reaction of nuciferine (VII) with metallic sodium in liquid ammonia was carried out and it was found that the methoxyl group in 1-position is liberated to form 2-methoxy-aporphine (VIII) which was identified with the specimen synthesized by another route. The same reaction of nornuciferine (IX) also resulted in the liberation of methoxyl in 1-position to form 2-hydroxyaporphine (X) but another substance (XI) was also obtained at the same time which seemed to have been formed by further progress of the reaction.

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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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