1972 年 92 巻 1 号 p. 108-110
Circular dichroism (CD) and optical rotatory dispersion (ORD) of peracetates of 1, 2-dideoxy-1-nitro alcohols, in which C-3 is the nearest asymmetric carbon to the nitro chromophore, were measured. Their CD curves showed a maximum at about 270 mμ. A second absorption band near 310 mμ was suggested by a tailing of the CD curves toward longer wavelengths. Compounds that have an acetoxyl group on the left side of C-3 in the conventional Fischer projection formula exhibited negative CD maxima, while a compound which has an acetoxyl group on the right side of C-3 showed a positive CD maximum.