Nitrene(第11報)Ethylα-Phenyl-2-nitrocinnamate誘導体と亜リン酸トリエチルとの反応(複素環式化合物の合成研究(第494報))

抄録

The reaction of ethyl trans-α-phenyl-2-nitrocinnamate derivative (XI) with triethyl phosphite gave a mixture of indole, quinoline, and carbostyril derivatives which were separated. The formation of quinoline and carbostyril derivatives proved that this reaction proceeded through an intermediate, the configuration of which was reversed.