チオピラゾロン誘導体の分析化学的研究(第10報)チオピリンの金属錯体について
1972 年 92 巻 10 号 p. 1252-1262
詳細
1972 年 92 巻 10 号 p. 1252-1262
A large number of metal complexes containing thiopyrine as a ligand was synthesized and their characteristics were clarified from the measurement of molar conductivity and molecular weight in nonaqueous solvent. Thiopyrine coordinates with metal ions, and in the presence of perchlorate ion, forms electrolyte complexes like [ZnT4](ClO4)2, [CdT4](ClO4)2, [CoT4](ClO4)2, [PbT4](ClO4)2, [HgT2](ClO4)2, [HgT4](ClO4)2, [CuT3](ClO4)2, [AgT] ClO4, and [AgT3]ClO4, where T stands for thiopyrine. In the presence of halogen and thiocyanate ion, MT2X2 type of nonelectrolyte complexes are formed from zinc (II), cadmium (II), mercury (II), and cobalt (II), ahd MT2X type complex from copper (I) and silver (I), Where T stands for thiopyrine, M for metal, and X is Cl, Br, I, or SCN.
