Serratinine誘導体の転位成績体の構造

抄録

Treatment of dehydrodeoxomonoacetate (VIII) with 90% H₂O₂-(CF₃CO)₂O gave a lactone acetate and treatment of the α, β-unsaturated ketone (XIII) with 10% NaOH-MeOH gave the phenolic base. The structures of these two rearrangement products, the lactone acetate and the pheno1ic base were deduced as B : R=Ac and XIV, respectively.