YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Dibenzothiepin誘導体およびその関連化合物 (第3報) Triphenylmethyl Hexachloroantimonate の反応性の研究と6,11-Dihydrodibenzo [b, e]-thiepin-11-ylium Hexachloroantimonate類の合成
堀 幹夫片岡 貞清水 洋小野木 和弘
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1978 年 98 巻 10 号 p. 1333-1340

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In order to examine the utility of triphenylmethyl hexachloroantimonate (1) for organic synthesis, various kinds of hexachloroantimonates of carbonium ion were prepared by the reaction of 1 with equimolar amount of various kinds of appropriate cyclic compounds. These products were obtained in a simple and stable manner compared to the synthesis of corresponding perchlorates. Experimental studies were also made on the limitation of 1 as an anion (H-, OH-, Cl-, etc.) abstraction reagent, using various kinds of 6, 11-dihydrodibenzo [b, e] thiepin derivatives.
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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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