有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
エナンチオ選択的なメソエポキシドの開環反応―ハロヒドリン化を中心に―
倉崎 晴彰
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ジャーナル オープンアクセス

2009 年 67 巻 1 号 p. 76-77

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The asymmetric ring opening of meso-epoxides with variety of nucleophiles is an important transformation to produce 1,2-bifunctionalized systems and to establish two contiguous stereogenic centers in a single event. This mini-review focuses on the recent advances in asymmetric ring opening of meso-epoxides with halogen-containing nucleophiles to afford the vicinal halohydrins. The vicinal halohydrins can be utilized for some useful synthetic transformations, and are also key imtermediates in the synthesis of natural products.

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© 2009 社団法人 有機合成化学協会
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