有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
総説および総合論文
銅-アセチリド錯体を鍵中間体として経由する触媒反応の最近の進展
服部 岳三宅 由寛西林 仁昭
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2011 年 69 巻 10 号 p. 1086-1098

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Recent progress in catalytic reactions via copper-acetylide complexes as key intermediates is reviewed from the viewpoint of organic synthesis. A variety of novel catalytic reactions such as cross-coupling reactions, addition reactions, and cycloaddition reactions using copper-acetylide complexes as carbon sources have been developed. Copper complexes bearing an optically active ligand promote various asymmetric transformations such as propargylic substitution reactions of propargylic esters and ring-opening reactions of ethynyl epoxides, where copper-allenylidene complexes work as key and common intermediates.

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© 2011 社団法人 有機合成化学協会
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