有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
エナミン誘導体の極性転換による炭素-炭素結合構築法
谷本 裕樹
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ジャーナル オープンアクセス

2011 年 69 巻 7 号 p. 823-824

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Umpolung chemistry has been the focus of research on organic synthesis due to its usefulness and unusual reactivity. Above all, umpolung of enamine property enables the formation of highly substituted carbon-carbon bonds and installation of aryl groups on sp3 carbon atoms, which are difficult to realize by normal enolate chemistry. This short review describes recent reports of the carbon-carbon bond formation by umpolung reactions of enamine derivatives.

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© 2011 社団法人 有機合成化学協会
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