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有機合成化学協会誌
Vol. 69 (2011) No. 7 P 823-824

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.69.823

Review de Debut

Umpolung chemistry has been the focus of research on organic synthesis due to its usefulness and unusual reactivity. Above all, umpolung of enamine property enables the formation of highly substituted carbon-carbon bonds and installation of aryl groups on sp3 carbon atoms, which are difficult to realize by normal enolate chemistry. This short review describes recent reports of the carbon-carbon bond formation by umpolung reactions of enamine derivatives.

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