有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
総説および総合論文
面不斉遷移金属錯体の触媒的不斉合成
荒江 祥永小笠原 正道
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2012 年 70 巻 6 号 p. 593-605

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Although “central chirality” based on stereogenic carbon atoms is arguably the most common chiral element in organic chemistry, chiral molecules devoid of stereogenic centers play important roles in stereoselective organic transformations. Among these chiral compounds withnon-centrochirality”, planar-chiral transition-metal complexes have been utilized as chiral ligands, chiral catalysts, or chiral building blocks in asymmetric synthesis. However, enantiomerically enriched forms of these compounds are primarily obtained by rather classical methods. Examples of catalytic enantioselective induction of planar-chirality in transition-metal species have been extremely rare and still a developing area in this field. In this review article, catalytic asymmetric synthesis of various “planar-chiral transition-metal complexes” are surveyed in a comprehensive manner.

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© 2012 社団法人 有機合成化学協会
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