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有機合成化学協会誌
Vol. 70 (2012) No. 6 p. 651-652

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.70.651

Review de Debut

Even in recent days, the SN2 reaction on vinylic carbons is not very common. This reaction pathway has been considered as an unlikely mechanism for a long time. However, recent investigations clearly indicate that nucleophilic attack on the σ* orbital of Csp2-LG bond is viable. In this short review, representative examples of this type of reaction are outlined.

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