有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
総説および総合論文
マイクロリアクターによる有機リチウム化学の新展開
永木 愛一郎
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ジャーナル 認証あり

2013 年 71 巻 10 号 p. 1002-1019

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Chemical synthesis in microreactors has received significant research interests both from academia and industry. Herein we report that organolithium reactions that are difficult to be done in batch can be achieved in flow microreactors. Characteristic features of flow microreactors such as precise residence time control are responsible for the control of unstable organolithiums. Protecting-group free synthesis and stereoselective synthesis using unstable organolithiums using flow microreactors serve as powerful tools in organic synthesis. Integration of such organolithium reactions also enhances the power and speed of organic synthesis and polymer synthesis.

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© 2013 社団法人 有機合成化学協会
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