Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
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New Approaches to the Regioselective Synthesis of Heteroaryl Triflones
Xiu-Hua XuNorio Shibata
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JOURNAL OPEN ACCESS

2013 Volume 71 Issue 11 Pages 1195-1201

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Abstract

Heteroaryl triflones are potential building blocks for the synthesis of novel biologically active compounds as well as functional materials. However, their synthesis has received relatively little attention. In this account, we describe our recent development of three novel synthetic strategies for the regioselective synthesis of heteroaryl triflones: direct trifluoromethanesulfonylation of heteroaromatic compounds, anionic Fries rearrangement of heteroaryl triflates, and transformation from triflyl-containing building blocks.

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© 2013 The Society of Synthetic Organic Chemistry, Japan
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