有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
メタ選択的な芳香族C-H結合の官能基化
五東 弘昭
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ジャーナル オープンアクセス

2013 年 71 巻 4 号 p. 355-356

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Substituted arenes are important building blocks for many natural products, medicines and materials. Functionalization of unactivated carbon-hydrogen (C-H) bonds is an efficient strategy for preparation of these compounds without substrate prefunctionalization. The traditional C-H activation methods utilized proximate heteroatom directing groups that direct selective cleavage of ortho C-H bonds and formconformationally rigid metallacycles. However, recent advances in the field have enabled meta-selective C-H functionalizations.

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© 2013 社団法人 有機合成化学協会
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