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有機合成化学協会誌
Vol. 71 (2013) No. 4 p. 355-356

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.71.355

Review de Debut

Substituted arenes are important building blocks for many natural products, medicines and materials. Functionalization of unactivated carbon-hydrogen (C-H) bonds is an efficient strategy for preparation of these compounds without substrate prefunctionalization. The traditional C-H activation methods utilized proximate heteroatom directing groups that direct selective cleavage of ortho C-H bonds and formconformationally rigid metallacycles. However, recent advances in the field have enabled meta-selective C-H functionalizations.

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